Modulation of the Molecular Structure of Tri-aryl Amine Fibrils in Hybrid Poly[vinyl chloride] Gel/Organogel Systems

This paper reports on the thermodynamics through mapping out temperature–concentration phase diagrams and molecular structure morphology of binary organogels prepared with trisamide triarylamine (TATA) in tetrachloroethane their ternary thermoreversible hybrid gels formed polyvinyl chloride (PVC). For low PVC contents, TATA organogel moiety behaves as systems, while for higher thermal behavior is significantly altered appearance a nonvariant event. The assemblies compared that observed bulk solid state. Three packings are bulk, whose crystalline lattices tentatively derived. Structure I obtained after crystallization–purification process seen to transform at temperature into II. By cooling, III obtained, which transforms reversibly II heating. metastability leads one contemplate possible formation compounds during presence chlorinated solvents, more so structures turn exhibit high similarities. Finally, observation reveals fibrils matrix can be well identified essentially observes fibrils.